
structural formula
| business number | 017u |
|---|---|
| molecular formula | c14h16clo5ps |
| molecular weight | 362.77 |
| label |
o-(3-chloro-4-methylcoumarin-7-yl)-o,o-diethylphosphorothioate, coumaphos, phosphorus, kuma fushi, agridip, baymix, coumafos, meldone, coumaphoscumafos, o-(3-chloro-4-methylcoumarin-7-yl)-o,o-diethyl phosphorothioate, organophosphorus pesticides |
numbering system
cas number:56-72-4
mdl number:mfcd00041820
einecs number:200-285-3
rtecs number:gn6300000
brn number:327083
pubchem number:24868876
physical property data
1. characteristics: colorless crystal. the industry is brown crystal
2. density (g/ml,25 /4℃): 1.474
3. relative vapor density (g/ml,air=1): undetermined
4. melting point ( ºc): 95℃
5. boiling point ( ºc,normal pressure): undetermined
6. boiling point ( ºc,5.2kpa): undetermined
7. refractive index: undetermined
8. flashpoint (ºc): undetermined
9. specific optical rotation (º): undetermined
10. autoignition point or ignition temperature (ºc): not ok
11. vapor pressure (kpa,25ºc this product should be kept sealed.
synthesis method
(1)200gethyl acetoacetate and270g so2ci2, respectively dissolved in100mlbenzene, then in10℃, so2ci2it is obtained by dropping a benzene solution into a benzene solution of ethyl acetoacetate. (2) resorcin88gandα-ethyl acetoacetate chloride132gdrip640mlin concentrated sulfuric acid, the temperature is 5produced by reaction below ℃3-chlorine-4-methyl-7-hydroxycoumarin. 44g 3-chlorine-4- methyl-7-hydroxycoumarin,29ganhydrous potassium carbonate is placed together500mlin methyl ethyl ketone, add dropwise under reflux and stirring40g o,o-diethylphosphorothioate chloride, reflux2h and get fly poison phosphorus.
purpose
fly poison phosphorus-based non-systemic insecticides are particularly effective against dipteran pests. they are also used to control external parasites and are effective in controlling skin flies.
mes new roman’; mso-hansi-font-family: ‘times new roman’; mso-bidi-font-family: arial”>in concentrated sulfuric acid, the temperature is 5obtained by reaction below ℃3-chlorine-4-methyl-7-hydroxycoumarin. 44g 3-chlorine-4- methyl-7-hydroxycoumarin,29ganhydrous potassium carbonate is placed together500mlin methyl ethyl ketone, add dropwise under reflux and stirring40g o,o-diethylphosphorothioate chloride, reflux2h and get fly poison phosphorus.
purpose
fly poison phosphorus-based non-systemic insecticides are particularly effective against dipteran pests. they are also used to control external parasites and are effective in controlling skin flies.
0.25pt; mso-bidi-font-family: arial”>

微信扫一扫打赏
